Profesores

Doctorovich, Fabio
Associate Professor UBA

CONICET: Investigador Independiente

INQUIMAE
Departamento de Química Inorgánica, Analítica, y Química Física
Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires
Tel.: 54-11- 4576-3378/80 ext. 116
Fax: 54-11- 4576-3341

Licenciatura in Chemistry, University of Buenos Aires, 1986
PhD. in Chemistry, University of Buenos Aires, 1990

Postdoctoral: Georgia Institute of Technology, 1990-1995

e-mail: doctorovich@qi.fcen.uba.ar

Fields of Interest:

Inorganic chemistry, Organometallic Chemistry
Electrophilic reactions of nitrosyl complexes
NO and HNO donors and traps
Porphyrin chemistry
Crystal engineering

Selected publications:

1. Hydrogen-Free Homogeneous Catalytic Reduction  of Olefins in Aqueous Solutions,
Gaviglio, C.; Doctorovich, F.
J. Org. Chem., 2008, 73, 5379-5384.

2. A Unique Family of Stable and Water-Soluble S-Nitrosothiol Complexes.
Perissinotti, L. L.;  Leitus, G.; Shimon, L.; Estrin, D.; Doctorovich, F.
Inorg. Chem. 2008, 47, 4723-4733.

3. Synthesis, structure and reactivity of aliphatic primary nitrosamines stabilized by coordination to [IrCl5]2-
Di Salvo, F.; Estrin, D. A.; Leitus, G.; Doctorovich, F.
Organometallics, 2008, 27, 1985-1995.

4. Performing Organic Chemistry with Inorganic Compounds: Electrophilic Reactivity of Selected Nitrosyl Complexes.
Doctorovich, F.; Di Salvo, F.
Acc. Chem. Res. 2007, 40, 985-993. Nombrado por la ACS como "Most-Accessed Article" del tercer trimestre (julio-setiembre) 2007.

5. Electronic Perturbation in a Molecular Wire of [IrCl5(NO)]- Units.
Di Salvo, F.; Escola, N.; Scherlis, D. A.; Estrin, D. A.; Bondía, C.; Murgida, D.; Ramallo-López, J. M.; Requejo, F. G.;  Shimon, L.; Doctorovich, F.
Chem. Eur. J., 2007, 13, 8428-8436.

6. Formation of Coordinated C-Nitroso Compounds by Reaction of K[IrCl5NO] with Alkenes.
Escola, N.; Llebaría, A.; Leitus, G.; Doctorovich, F.
Organometallics, 2006, 25, 3799-3801.

7. A Surprisingly Stable S-Nitrosothiol Complex,
Perissinotti, L.; Estrin D.; Leitus, G.; Doctorovich, F.
J. Am. Chem. Soc. 2006, 128, 2512-2513.

8. Formation of Coordinated Nitrosamines by Reaction of K[IrCl5NO] with Primary Amines
Doctorovich, F.; Di Salvo, F.; Escola, N.; Trápani, C.; Shimon, L.
Organometallics, 2005, 24, 4707-4709.

9. Discrimination of Nitroxyl and Nitric Oxide by Soluble Mn(III) Porphyrins
Martí, M.; Bari, S. E.; Estrin, D. A.; Doctorovich, F.
J. Am. Chem. Soc. 2005, 127, 4680-4684.